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. 2013 May 3;78(9):4251-60.
doi: 10.1021/jo400041p. Epub 2013 Apr 18.

Total syntheses of the proposed structure for ieodoglucomides A and B

Chada Raji Reddy  1 , Enukonda Jithender, Kothakonda Rajendra Prasad
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Total syntheses of the proposed structure for ieodoglucomides A and B

Chada Raji Reddy et al. J Org Chem. .

Abstract

The first enantioselective total synthesis of new glycolipopeptides, ieodoglucomides A and B, has been accomplished along with synthetic elaboration to their C14-epimers starting from d-glucose using β-glycosylation and Grubbs olefin cross-metathesis reactions as the key steps. The present synthetic study has indicated the ambiguity in proposed absolute stereochemistry for the natural product.

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