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. 2013 May 17;15(10):2334-7.
doi: 10.1021/ol400437a. Epub 2013 Apr 26.

Synthesis of 2-aminophenols and heterocycles by Ru-catalyzed C-H mono- and dihydroxylation

Xinglin Yang  1 , Gang Shan, Yu Rao
Affiliations

Synthesis of 2-aminophenols and heterocycles by Ru-catalyzed C-H mono- and dihydroxylation

Xinglin Yang et al. Org Lett. .

Abstract

A novel and efficient synthesis of 2-aminophenols, 2-aminobenzene-1,3-diols, and heterocycles through Ru-catalyzed C-H mono- and dihydroxylation of anilides has been developed with a new directing group strategy. The reaction demonstrates excellent reactivity, regioselectivity, good functional group tolerance, and high yields.

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