Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2013 Mar 6;69(Pt 4):m187-8.
doi: 10.1107/S1600536813005096. Print 2013 Apr 1.

2-Meth-oxy-anilinium trichlorido-stannate(II)

Sahel Karoui  1 , Slaheddine Kamoun, François Michaud
Affiliations

2-Meth-oxy-anilinium trichlorido-stannate(II)

Sahel Karoui et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title compound, (C7H10NO)[SnCl3], is a new compound with non-linear optical (NLO) properties. The structure is pseudocentrosymmetric; the absence of an inversion centre was proved by the Kurtz and Perry method showing a significant second harmonic generation (SHG) signal about ten times lower than that from potassium dihydrogenphosphate. The crystal structure exhibits alternating organic and inorganic layers parallel to the ab plane, which are stabilized by inter-molecular N-H⋯Cl inter-actions.

PubMed Disclaimer

Figures

Fig. 1.
Fig. 1.
Perspective view of the title compound with displacement ellipsoids drawn at the 50% probability level and H atoms represented by small spheres of arbitrary radii.
Fig. 2.
Fig. 2.
The crystal packing of the title compound viewed along the [100] axis showing the hydrogen bonding network.
See this image and copyright information in PMC

References

    1. Agilent (2012). CrysAlis PRO and CrysAlis RED Agilent Technologies, Yarnton, England.
    1. Ben Gozlen, M. H., Kamoun, S., Paulush, H. & Pabst, I. (1994). Z. Kristallogr. 209, 382–382.
    1. Brandenburg, K. & Berndt, M. (1999). DIAMOND Crystal Impact GbR, Bonn, Germany.
    1. Domenicano, A. & Murray-Rust, P. (1979). Tetrahedron Lett. 20, 2283–2286.
    1. Farrugia, L. J. (2012). J. Appl. Cryst. 45, 849–854.