Switchable catalytic activity: selenium-containing peptides with redox-controllable self-assembly properties
- PMID: 23784972
- DOI: 10.1002/anie.201303199
Switchable catalytic activity: selenium-containing peptides with redox-controllable self-assembly properties
Abstract
Mimicking nature: The reversible formation of self-assembled nanostructures of selenium-containing peptides can be controlled by redox triggers (see scheme, VC = vitamin C). As a consequence, the catalytic activity of these peptides is switchable. These results should lead to the development of nature-mimicking smart materials with promising properties.
Keywords: hydrogels; peptides; redox chemistry; selenium; self-assembly.
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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