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. 2013 Jul 10;135(27):10018-21.
doi: 10.1021/ja404072w. Epub 2013 Jun 27.

Self-assembled containers based on extended tetrathiafulvalene

Sébastien Bivaud  1 , Sébastien Goeb, Vincent Croué, Paul I Dron, Magali Allain, Marc Sallé
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Self-assembled containers based on extended tetrathiafulvalene

Sébastien Bivaud et al. J Am Chem Soc. .

Abstract

Two original self-assembled containers constituted each by six electroactive subunits are described. They are synthesized from a concave tetratopic π-extended tetrathiafulvalene ligand bearing four pyridyl units and cis-M(dppf)(OTf)2 (M = Pd or Pt; dppf = 1,1'-bis(diphenylphosphino)ferrocene; OTf = trifluoromethane-sulfonate) complexes. Both fully characterized assemblies present an oblate spheroidal cavity that can incorporate one perylene molecule.

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