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. 2013 Jul 19;15(14):3706-9.
doi: 10.1021/ol401569u. Epub 2013 Jul 3.

Rhodium(III)-catalyzed C-H activation and amidation of arenes using N-arenesulfonated imides as amidating reagents

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Rhodium(III)-catalyzed C-H activation and amidation of arenes using N-arenesulfonated imides as amidating reagents

Songjie Yu et al. Org Lett. .

Abstract

Rhodium(III)-catalyzed C-H activation-amidation of arenes bearing chelating groups has been achieved using N-arenesulfonated imides as efficient amidating reagents without using any base additive. Pyridine, oxime, and pyrimidine proved to be viable directing groups.

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