Rhodium(III)-catalyzed C-H activation and amidation of arenes using N-arenesulfonated imides as amidating reagents
- PMID: 23822068
- DOI: 10.1021/ol401569u
Rhodium(III)-catalyzed C-H activation and amidation of arenes using N-arenesulfonated imides as amidating reagents
Abstract
Rhodium(III)-catalyzed C-H activation-amidation of arenes bearing chelating groups has been achieved using N-arenesulfonated imides as efficient amidating reagents without using any base additive. Pyridine, oxime, and pyrimidine proved to be viable directing groups.
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