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. 2013 Sep 16;52(38):10056-9.
doi: 10.1002/anie.201304591. Epub 2013 Aug 9.

Palladium-catalyzed intermolecular asymmetric allylic dearomatization reaction of naphthol derivatives

Chun-Xiang Zhuo  1 , Shu-Li You
Affiliations

Palladium-catalyzed intermolecular asymmetric allylic dearomatization reaction of naphthol derivatives

Chun-Xiang Zhuo et al. Angew Chem Int Ed Engl. .

Abstract

Baring all: The title reaction provides β-naphthalenones bearing an all-carbon quaternary center in good to excellent yields, as well as excellent chemo- and enantioselectivity.

Keywords: allylic dearomatization; arenes; asymmetric catalysis; palladium; synthetic methods.

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