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. 2013 Oct 25;49(83):9651-3.
doi: 10.1039/c3cc45350b.

Ruthenium-catalyzed oxidative ortho-benzoxylation of acetanilides with aromatic acids

Kishor Padala  1 , Masilamani Jeganmohan
Affiliations

Ruthenium-catalyzed oxidative ortho-benzoxylation of acetanilides with aromatic acids

Kishor Padala et al. Chem Commun (Camb). .

Abstract

Substituted acetanilides reacted with aromatic acids in the presence of [{RuCl2(p-cymene)}2], AgSbF6 and (NH4)2S2O8 in ClCH2CH2Cl at 100 °C for 24 h yielding ortho-benzoxylated acetanilides in good to excellent yields in a highly regioselective manner via C-H bond activation.

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