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. 2013 Jun 8;69(Pt 7):m353.
doi: 10.1107/S1600536813014335. eCollection 2013.

Tris(N,N-di-methyl-anilinium) tri-μ-bromido-bis[tribromido-anti-monate(III)]

Houda Kharrat  1 , Slaheddine Kamoun, François Michaud
Affiliations

Tris(N,N-di-methyl-anilinium) tri-μ-bromido-bis[tribromido-anti-monate(III)]

Houda Kharrat et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, (C8H12N)3[Sb2Br9], two of the three unique N,N-dimethyanilinium cations exhibit flip-flop disorder with an occupancy ratio of 0.58 (1):0.42 (1). N-H⋯Br hydrogen bonds link the organic cations and bioctahedral face-sharing anions into a three-dimensional network.

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Figures

Fig. 1.
Fig. 1.
The asymmetric part of the unit cell of (C8H12N)3Sb2Br9 crystal at 296 (2) K with the atom labeling scheme.
Fig. 2.
Fig. 2.
The crystal packing of (C8H12N)3Sb2Br9 showing the hydrogen bonding network as blue dashed lines.
See this image and copyright information in PMC

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