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. 2013 Jun 29;69(Pt 7):o1165.
doi: 10.1107/S1600536813017285. eCollection 2013.

8-Phenyl-16-thia-penta-cyclo-[6.6.5.0(1,18).0(2,7).0(9,14)]nona-deca-2,4,6,9,11,13,18-hepta-ene

Eason M Mathew  1 , M Sithambaresan, P A Unnikrishnan, M R Prathapachandra Kurup
Affiliations

8-Phenyl-16-thia-penta-cyclo-[6.6.5.0(1,18).0(2,7).0(9,14)]nona-deca-2,4,6,9,11,13,18-hepta-ene

Eason M Mathew et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, C24H18S, the dihedral angles between the phenyl ring and the two benzene rings of the anthracene moiety are 51.92 (9) and 68.24 (9)°, whereas the dihedral angle between the two anthracene benzene rings is 120.13 (9)°. The three non-aromatic six-membered rings are in boat conformations, while the five-membered ring has an envelope conformation on the S atom. In the crystal, there are three C-H⋯π inter-actions, which facilitate the packing of the mol-ecules.

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Figures

Fig. 1.
Fig. 1.
ORTEP view of the title compound drawn with 50% probability displacement ellipsoids for the non-H atoms.
Fig. 2.
Fig. 2.
C—H···π interactions found in the title compound.
Fig. 3.
Fig. 3.
Packing diagram of the compound along b axis.
See this image and copyright information in PMC

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