Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2013 Sep 4;69(Pt 10):m527.
doi: 10.1107/S1600536813024288. eCollection 2013.

Tri-carbonyl-chlorido-(6',7'-di-hydro-5'H-spiro-[cyclo-hexane-1,6'-dipyrido[3,2-d:2',3'-f][1,3]diazepine]-κ(2) N (1),N (11))rhenium(I)

Oliver R Clegg  1 , Lindsay P Harding, John W Miller, Craig R Rice
Affiliations

Tri-carbonyl-chlorido-(6',7'-di-hydro-5'H-spiro-[cyclo-hexane-1,6'-dipyrido[3,2-d:2',3'-f][1,3]diazepine]-κ(2) N (1),N (11))rhenium(I)

Oliver R Clegg et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, [ReCl(C16H18N4)(CO)3], the Re(I) ion is coordinated in a distorted octa-hedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclo-hexane group is orientated in a transoid fashion with respect to the chloride ligand. In the crystal, N-H⋯Cl hydrogen bonds link complex mol-ecules, forming a two-dimensional network parallel to (100).

PubMed Disclaimer

Figures

Fig. 1.
Fig. 1.
The molecular structure of the title compound with displacement ellipsoids shown at the 50% probability level.
See this image and copyright information in PMC

References

    1. Bruker (2009). APEX2, SAINT and SADABS . Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Bullock, S., Hallett, A. J., Harding, L. P., Higginson, J. J., Piela, S. A. F., Pope, S. J. A. & Rice, C. R. (2012). Dalton Trans. 41, 14690–14696. - PubMed
    1. Clayton, H. J., Harding, L. P., Irvine, J. P., Jeffery, J. C., Riis-Johannessen, T., Laws, A. P., Rice, C. R. & Whitehead, M. (2008). Chem. Commun. pp. 108–110. - PubMed
    1. Clegg, O. R., Harding, L. P., Miller, J. W. & Rice, C. R. (2013). Acta Cryst. E69, m526. - PMC - PubMed
    1. Coleman, A., Brennan, C., Vos, J. G. & Pryce, M. T. (2008). Coord. Chem. Rev. 252, 2585–2595.