2,2'-{[(1E,1'E)-(Cyclo-hexane-1,4-diyl)-bis(aza-nylyl-idene)]bis-(ethan-1-yl-1-yl-idene)}diphenol

Abstract

The title compound, C22H26N2O2, crystallizes with three independent mol-ecules, two of which are situated on inversion centers, so the asymmetric unit contains two independent half-mol-ecules and one mol-ecule in a general position. The two hy-droxy groups in each mol-ecule are involved in intra-molecular O-H⋯N hydrogen bonds, which generate S(6) rings. In the crystal, weak inter-molecular C-H⋯π inter-actions link the mol-ecules into two crystallographically independent columns propagating along [001]; one column consists of mol-ecules in general positions, while the other column is built from alternating independent centrosymmetric mol-ecules.

Fig. 1.

Three crystallographically independent molecules showing the atomic numbering and 30% probability displacement ellipsoids [symmetry codes: (a) -x, 1 - y, -z; (b) 2 - x, 1 - y, 1 - z]. H atoms omitted for clarity.