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. 2013 Oct 18;15(20):5286-9.
doi: 10.1021/ol402515s. Epub 2013 Oct 7.

Ru(II)-catalyzed ortho-C-H amination of arenes and heteroarenes at room temperature

Ming Shang  1 , Shao-Hang Zeng, Shang-Zheng Sun, Hui-Xiong Dai, Jin-Quan Yu
Affiliations

Ru(II)-catalyzed ortho-C-H amination of arenes and heteroarenes at room temperature

Ming Shang et al. Org Lett. .

Abstract

The Ru(II)-catalyzed ortho-C-H amination directed by a weakly coordinating amide auxiliary with O-benzoyl hydroxylamines at room temperature has been achieved. This reaction is compatible with heterocycles including pyrazole, thiophene, benzothiophene, furan, benzofuran, and indole.

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