Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2013 Jul 20;69(Pt 8):o1280.
doi: 10.1107/S1600536813019545. eCollection 2013.

N,N-Diethyl-4-[(E)-(pyridin-3-yl)diazen-yl]aniline

Affiliations

N,N-Diethyl-4-[(E)-(pyridin-3-yl)diazen-yl]aniline

Sergiu Draguta et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The mol-ecule of the title compound, C15H18N4, adopts a trans conformation with respect to the diazo N=N bond. The dihedral angle between the benzene and pyridine rings in the mol-ecule is 8.03 (5)°. In the crystal, a weak C-H⋯π inter-action arranges the mol-ecules into a corrugated ribbon, with an anti-parallel orientation of neighboring mol-ecules propagating in the [100] direction.

PubMed Disclaimer

Figures

Fig. 1.
Fig. 1.
Molecular structure of I. Displacement ellipsoids are shown at the 50% probability level. H atoms are presented as small spheres of arbitrary radius.
Fig. 2.
Fig. 2.
A portion of the crystal packing, showing the weak C—H···π interactions by dashed lines.

References

    1. Bruker (2001). SAINT Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Bruker (2005). APEX2 Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Chemla, D. S. & Zyss, J. (1987). Nonlinear Optical Properties of Organic Molecules and Crystals, Vol. 1, pp. 232–277. New York: Academic Press.
    1. Draguta, S., Khrustalev, V. N., Fonari, M. S., Antipin, M. Y. & Timofeeva, T. V. (2012). Acta Cryst. E68, o3353. - PMC - PubMed
    1. Forrest, S., Burrows, P., Stroustrup, A., Strickland, D. & Ban, V. (1996). Appl. Phys. Lett. 68, 1326–1332.