Observing the formation and the reactivity of an octahedral iron(V) nitrido complex in real time
- PMID: 24127281
- DOI: 10.1002/anie.201306621
Observing the formation and the reactivity of an octahedral iron(V) nitrido complex in real time
Abstract
Give me five: Time-resolved Fourier-transform IR spectroscopy is used to time-resolve the formation and the reaction dynamics of a fourfold symmetrical nitrido iron(V) complex (light blue C, red Fe, blue N) in liquid solution under physiological and technologically relevant conditions.
Keywords: IR spectroscopy; high-valent iron; nitride; photochemistry; time-resolved spectroscopy.
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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