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. 2013 Dec 20;15(24):6186-9.
doi: 10.1021/ol403028a. Epub 2013 Nov 11.

Pd(II)-catalyzed C(sp2)-H hydroxylation with R2(O)P-coordinating group

Hong-Yu Zhang  1 , Hong-Ming Yi, Gang-Wei Wang, Bin Yang, Shang-Dong Yang
Affiliations

Pd(II)-catalyzed C(sp2)-H hydroxylation with R2(O)P-coordinating group

Hong-Yu Zhang et al. Org Lett. .

Abstract

A novel R2(O)P-directed Pd(II)-catalyzed C-H hydroxylation to synthesize various substituted 2'-phosphorylbiphenyl-2-ol compounds is described. Notably, the reaction operates under mild conditions and shows good functional group tolerance, high selectivity, and yield.

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