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. 2014 Jan 13;53(3):725-8.
doi: 10.1002/anie.201307051. Epub 2013 Dec 4.

The photoredox-catalyzed Meerwein addition reaction: intermolecular amino-arylation of alkenes

Durga Prasad Hari  1 , Thea Hering, Burkhard König
Affiliations

The photoredox-catalyzed Meerwein addition reaction: intermolecular amino-arylation of alkenes

Durga Prasad Hari et al. Angew Chem Int Ed Engl. .

Abstract

A variety of amides are efficiently accessible under mild conditions by intermolecular amino-arylation using a photo Meerwein addition with visible light. The reaction has a broad substrate scope, tolerates a large range of functional groups, and was applied to the synthesis of a 3-aryl-3,4-dihydroisoquinoline.

Keywords: Meerwein addition; amino-arylation; aryl radicals; photocatalysis; visible light.

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