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. 2013 Dec 15;69(Pt 12):1482-4.
doi: 10.1107/S0108270113029776. Epub 2013 Nov 8.

(OC-6-13)-difluoridooxidobis(propan-2-ol)(propan-2-olato)vanadium(V)

Julia Kohl  1 , Dennis Wiedemann
Affiliations

(OC-6-13)-difluoridooxidobis(propan-2-ol)(propan-2-olato)vanadium(V)

Julia Kohl et al. Acta Crystallogr C. .

Abstract

The distorted octahedral title complex, [V(V)(C3H7O)(C3H8O)2F2O], was synthesized via ligand exchange at [V(V)O(OiPr)3] with aqueous hydrogen fluoride in propan-2-ol and crystallized from (D)chloroform at 238 K after a few weeks. Crystal structure determination shows two C1-symmetric moieties to be present in the asymmetric unit, forming infinite chains along [100] via hydrogen bonds. The compound provides the first crystal structure containing the [VF2O(OiPr)] motif.

Keywords: alcoholates; crystal structure; hydrogen bonds; hydrogen fluoride; vanadium complexes.

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