Sulfate templated assembly of neutral receptors in aqueous DMSO - orthogonal versus biplane structures
- PMID: 24336487
- DOI: 10.1039/c3cc48463g
Sulfate templated assembly of neutral receptors in aqueous DMSO - orthogonal versus biplane structures
Abstract
Simple, easily available diamidocarbazoles form robust 2 : 1 complexes with SO4(2-) even in the presence of a large excess of water. An appropriate choice of side arms directs the assembly towards the formation of either an orthogonal or a biplane structure, both in solution and in the solid state.
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