doi: 10.1039/c3cc47769j.
Ethene/alkyne exchange reaction at an intramolecular frustrated Lewis pair
Affiliations
- PMID: 24409458
- DOI: 10.1039/c3cc47769j
Item in Clipboard
Ethene/alkyne exchange reaction at an intramolecular frustrated Lewis pair
Chem Commun (Camb).
.
Abstract
A vicinal ethylene bridged S/B frustrated Lewis pair (FLP) in situ generated by a hydroboration reaction of phenyl vinyl sulfide, reacts with p-tert-butylphenylacetylene by ethene/alkyne exchange and subsequent 1,2-addition of a second alkyne equivalent to give a zwitterionic sulfonium/borate product.
Similar articles
-
Frustrated Lewis pair modification by 1,1-carboboration: disclosure of a phosphine oxide triggered nitrogen monoxide addition to an intramolecular P/B frustrated Lewis pair.J Am Chem Soc. 2014 Jun 25;136(25):9014-27. doi: 10.1021/ja5028293. Epub 2014 Jun 16. J Am Chem Soc. 2014. PMID: 24850528
-
Functionalization of Intramolecular Frustrated Lewis Pairs by 1,1-Carboboration with Conjugated Enynes.Chemistry. 2015 Aug 24;21(35):12456-64. doi: 10.1002/chem.201502278. Epub 2015 Aug 4. Chemistry. 2015. PMID: 26284948
-
Addition reactions to the intramolecular mesityl2P-CH2-CH2-B(C6F5)2 frustrated Lewis pair.Dalton Trans. 2010 Aug 28;39(32):7556-64. doi: 10.1039/c0dt00015a. Epub 2010 Jul 8. Dalton Trans. 2010. PMID: 20617234
-
Noninteracting, vicinal frustrated P/B-Lewis pair at the norbornane framework: synthesis, characterization, and reactions.J Am Chem Soc. 2013 Jun 19;135(24):8882-95. doi: 10.1021/ja400338e. Epub 2013 Jun 7. J Am Chem Soc. 2013. PMID: 23627402
-
An Ethylene-Bridged Phosphane/Borane Frustrated Lewis Pair Featuring the -B(Fxyl)2 Lewis Acid Component.Chemistry. 2016 Jul 25;22(31):11015-21. doi: 10.1002/chem.201601583. Epub 2016 Jun 29. Chemistry. 2016. PMID: 27355412
Cited by
-
N-Geminal P/Al Lewis Pair-Alkyne Dipolar Cycloaddition to the Zwitterionic C2PNAl-Heterocyclopentene.ACS Omega. 2017 Jun 1;2(6):2405-2414. doi: 10.1021/acsomega.7b00236. eCollection 2017 Jun 30. ACS Omega. 2017. PMID: 31457589 Free PMC article.
-
Bismuth Meets Olefins: Ethylene Activation and Reversible Alkene Insertion into Bi─N Bonds.Angew Chem Int Ed Engl. 2025 Jun 24;64(26):e202505434. doi: 10.1002/anie.202505434. Epub 2025 May 8. Angew Chem Int Ed Engl. 2025. PMID: 40239098 Free PMC article.
-
Advanced 1,1-carboboration reactions with pentafluorophenylboranes.Chem Sci. 2016 Jan 1;7(1):56-65. doi: 10.1039/c5sc03282b. Epub 2015 Oct 8. Chem Sci. 2016. PMID: 28757997 Free PMC article.
LinkOut - more resources
Full Text Sources
Other Literature Sources
