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. 2013 Aug 17;69(Pt 9):m497.
doi: 10.1107/S1600536813022472. eCollection 2013.

Triphen-yl(pyrrolidine-1-carbodi-thio-ato-κS)tin(IV)

Muhammad Sirajuddin  1 , Noor Uddin  1 , Saqib Ali  1
Affiliations

Triphen-yl(pyrrolidine-1-carbodi-thio-ato-κS)tin(IV)

Muhammad Sirajuddin et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, [Sn(C6H5)3(C5H8NS2)], the Sn(IV) atom adopts a distorted SnC3S tetra-hedral coordination geometry [spread of bond angles = 94.43 (7)-120.74 (7)°]. A short intra-molecular Sn⋯S contact [3.0270 (9) Å] occurs and two intra-molecular C-H⋯S inter-actions help to establish the conformation. Three of the methyl-ene groups of the pyrrolidine-1-carbodi-thio-ate ligand are disordered over two sets of sites of equal occupancy. In the crystal, very weak C-H⋯S inter-actions link the mol-ecules into a three-dimensional network, with both S atoms acting as acceptors.

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Figures

Fig. 1.
Fig. 1.
View of the title compound with displacement ellipsoids drawn at the 50% probability level.
Fig. 2.
Fig. 2.
The partial packing, which shows that molecules form dimers due to C—H···S bonds.
See this image and copyright information in PMC

References

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    1. Pellerito, L. & Nagy, L. (2002). Coord. Chem. Rev. 224, 111–150.

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