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. 2013 Nov 30;69(Pt 12):o1858.
doi: 10.1107/S1600536813032066.

(S)-4,5-Diphenyl-1-[1-phenyl-3-(phenyl-sulfan-yl)propan-2-yl]-2-(thio-phen-2-yl)-1H-imidazole

Jie Gao  1 , Hongyan Wang  1 , Liangru Yang  1 , Yongmei Xiao  1 , Pu Mao  1
Affiliations

(S)-4,5-Diphenyl-1-[1-phenyl-3-(phenyl-sulfan-yl)propan-2-yl]-2-(thio-phen-2-yl)-1H-imidazole

Jie Gao et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, C34H28N2S2, the central imidazole ring (r.m.s. deviation = 0.0015 Å) forms dihedral angles of 55.7 (3), 17.94 (11) and 86.27 (11)°, respectively, with the mean planes of the attached thienyl and two phenyl substituents. The thienyl ring shows ring-flip disorder [occupancy ratio = 0.647 (2):0.353 (2)]. The chiral centre maintains the S configuration of the l-phenyl-alaninol starting material. Intra- and inter-molecular C-H⋯S hydrogen bonds involving the disordered thienyl ring are observed.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of the title compound showing 30% probability displacement ellipsoids. Hydrogen atoms, except for that associated to the chiral C22 atom, are omitted for clarity.
See this image and copyright information in PMC

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