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. 2013 Oct 5;69(Pt 11):o1608.
doi: 10.1107/S1600536813025889. eCollection 2013 Nov 1.

2-(4-Fluoro-phen-yl)-4-(thio-phen-2-yl)-2,3-di-hydro-1,5-benzothia-zepine

M Manjula  1 , B C Manjunath  1 , N Renuka  2 , K Ajay Kumar  2 , N K Lokanath  1
Affiliations

2-(4-Fluoro-phen-yl)-4-(thio-phen-2-yl)-2,3-di-hydro-1,5-benzothia-zepine

M Manjula et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, C19H14FNS2, the seven-membered thia-zepine ring adopts a slightly distorted twist boat conformation. The dihedral angle between the benzene rings is 53.6 (1)°. The mean plane of the thia-zepine ring is twisted by 34.3 (7)° and 36.6 (7)° from the benezene rings. A C-H⋯F interaction generates stacking of molecules along the ab plane.

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Figures

Fig. 1.
Fig. 1.
ORTEP diagram of the title molecule, C19H14FNS2, with 50% probability ellipsoids.
Fig. 2.
Fig. 2.
Hydrogen-bond (supramolecular architecure) interactions in the title compound.
See this image and copyright information in PMC

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