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. 2014 Apr 18;50(30):3976-8.
doi: 10.1039/c4cc00402g. Epub 2014 Mar 10.

A copper-catalyzed formal O-H insertion reaction of α-diazo-1,3-dicarbonyl compounds to carboxylic acids with the assistance of isocyanide

Zikun Wang  1 , Xihe Bi, Yongjiu Liang, Peiqiu Liao, Dewen Dong
Affiliations

A copper-catalyzed formal O-H insertion reaction of α-diazo-1,3-dicarbonyl compounds to carboxylic acids with the assistance of isocyanide

Zikun Wang et al. Chem Commun (Camb). .

Abstract

A novel copper-catalyzed formal O-H insertion of α-diazo-1,3-dicarbonyl compounds to carboxylic acids has been developed, providing a straightforward synthetic method for α-acyloxy-1,3-dicarbonyl compounds, in which the activation of carboxylic acids by isocyanide plays a crucial role.

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