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. 2014 Apr 28;43(16):5998-6001.
doi: 10.1039/c4dt00257a.

Self-assembly of a 15-nickel metallamacrocyclic complex derived from the L-glutamic acid Schiff base ligand

Yude Thio  1 , Shi Wei Toh, Feng Xue, Jagadese J Vittal
Affiliations

Self-assembly of a 15-nickel metallamacrocyclic complex derived from the L-glutamic acid Schiff base ligand

Yude Thio et al. Dalton Trans. .

Abstract

An intriguing 15-nickel metallamacrocyclic complex, [Ni15(EVan)10(H2O)20], (EVan = Schiff base formed between l-glutamic acid and o-vanillin), has been synthesized and characterized by single-crystal X-ray diffraction and spectroscopic analyses. adopts a Ni-O-Ni-O-Ni-O configuration and can be divided into five discrete trinuclear units.

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