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. 2014 Apr 28;50(33):4344-6.
doi: 10.1039/c4cc00550c.

Synthesis of a guanidine NHC complex and its application in borylation reactions

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Synthesis of a guanidine NHC complex and its application in borylation reactions

Chia-Cheng Tai et al. Chem Commun (Camb). .

Abstract

Synthesis of guanidine-linked NHC can be achieved easily through reacting amino-NHC with carbodiimide. Subsequently, guanidine-NHC Ag and Cu complexes were isolated and fully characterized. These Cu complexes are found to be versatile catalysts for hydroboration, semihydrogenation and carboboration of alkynes in a highly stereo- and regioselective fashion.

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