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. 2014 May 26;53(22):5657-61.
doi: 10.1002/anie.201400612. Epub 2014 Apr 16.

CO/C-H as an acylating reagent: a palladium-catalyzed aerobic oxidative carbonylative esterification of alcohols

Lu Wang  1 , Yanxia Wang, Chao Liu, Aiwen Lei
Affiliations

CO/C-H as an acylating reagent: a palladium-catalyzed aerobic oxidative carbonylative esterification of alcohols

Lu Wang et al. Angew Chem Int Ed Engl. .

Abstract

A palladium-catalyzed oxidative carbonylative esterification of a variety of functionalized alcohols under base- and ligand-free conditions has been demonstrated. A CO/olefin combination was utilized as the acylating reagent with O2 as a benign oxidant. Notably, the scope of the substrate alcohols has been greatly broadened.

Keywords: alcohols; esterification; oxidation; palladium; synthetic methods.

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