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. 2014 Feb 5;70(Pt 3):o248-9.
doi: 10.1107/S1600536814002189. eCollection 2014 Mar 1.

N-(12-Amino-9,10-di-hydro-9,10-ethano-anthracen-11-yl)-4-methyl-benzene-sulfonamide

Joel T Mague  1 , Alaa A-M Abdel-Aziz  2 , Adel S El-Azab  3 , Magda A El-Sherbeny  4
Affiliations

N-(12-Amino-9,10-di-hydro-9,10-ethano-anthracen-11-yl)-4-methyl-benzene-sulfonamide

Joel T Mague et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title compound, C23H22N2O2S, crystallizes with the 4-methyl-benzene-sulfonamide entity oriented towards the center of the bridgehead C atoms with a C-N-S-C torsion angle of -61.3 (2)°. The mol-ecule features an intra-molecular N-H⋯N hydrogen bond. Weak C-H⋯O and C-H⋯π inter-actions aid in forming the three-dimensional supra-molecular structure.

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Figures

Fig. 1.
Fig. 1.
Perspective view of the title molecule showing the intramolecular hydrogen bond. Displacement ellipsoids are drawn at the 50% probability level.
Fig. 2.
Fig. 2.
Packing diagram viewed down b with intermolecular interactions shown as dotted lines (C—H···O, purple; C—H···π, green).
See this image and copyright information in PMC

References

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