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. 2014 Feb 26;70(Pt 3):o359.
doi: 10.1107/S1600536814003948. eCollection 2014 Mar 1.

2-Cyclo-heptyl-idene-N-phenyl-hydrazine-carbo-thio-amide

Affiliations

2-Cyclo-heptyl-idene-N-phenyl-hydrazine-carbo-thio-amide

Mehmet Akkurt et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, C14H19N3S, the seven-membered cyclo-heptane ring adopts a chair conformation. An intra-molecular N-H⋯N hydrogen bond [graph-set motif S(5)] is present in the N-N-C-N chain between the ring systems. An intra-molecular C-H⋯S contact also occurs. In the crystal, pairs of mol-ecules form centrosymmetric dimers through N-H⋯S hydrogen bonds [graph-set R 2 (2)(8)]. These dimers are connected by C-H⋯S inter-actions with an R 2 (2)(14) motif.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of the title compound with 50% probability displacement ellipsoids.
Fig. 2.
Fig. 2.
View of the centrosymmetric R22(8) dimers of the title compound viewed down b-axis. H atoms not involved in hydrogen bonding have been omitted for clarity.

References

    1. Ali, M. A. & Livingstone, S. E. (1974). Coord. Chem. Rev. 13, 101–132.
    1. Bernstein, J., Davis, R. E., Shimoni, L. & Chang, N.-L. (1995). Angew. Chem. Int. Ed. Engl. 34, 1555–1573.
    1. Bruker (2013). APEX2, SAINT and SADABS Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Cremer, D. & Pople, J. A. (1975). J. Am. Chem. Soc. 97, 1354–1358.
    1. Du, X., Guo, C., Hansall, E., Doyle, P. S., Caffrey, C. R., Holler, T. P., McKerrov, J. H. & Cohen, F. E. (2002). J. Med. Chem. 45, 2695–2707. - PubMed