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. 2014 Jun 18;50(48):6333-6.
doi: 10.1039/c4cc01262c.

Iridium-catalysed borylation of sterically hindered C(sp³)-H bonds: remarkable rate acceleration by a catalytic amount of potassium tert-butoxide

Toshimichi Ohmura  1 , Takeru Torigoe, Michinori Suginome
Affiliations

Iridium-catalysed borylation of sterically hindered C(sp³)-H bonds: remarkable rate acceleration by a catalytic amount of potassium tert-butoxide

Toshimichi Ohmura et al. Chem Commun (Camb). .

Abstract

The C(sp(3))-H bonds located on the methyl groups of an isopropyl group participate in iridium-catalysed C-H borylation with bis(pinacolato)diboron via a significant rate acceleration caused by a catalytic amount of t-BuOK.

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