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. 2014 May 16;16(10):2664-7.
doi: 10.1021/ol500876x. Epub 2014 May 6.

Arylalkene synthesis via decarboxylative cross-coupling of alkenyl halides

Jie Tang  1 , Lukas J Goossen
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Arylalkene synthesis via decarboxylative cross-coupling of alkenyl halides

Jie Tang et al. Org Lett. .

Abstract

A bimetallic catalyst system generated from readily available palladium(II) and copper(I) salts, 1,10-phenanthroline and tri-1-naphthylphosphine was found to efficiently mediate the decarboxylative cross-coupling of alkenyl bromides and chlorides with aromatic carboxylates. It allows the regiospecific synthesis of a broad range of aryl- and heteroarylalkenes in high yields.

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