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. 2014 Jun 6;16(11):2896-9.
doi: 10.1021/ol501039u. Epub 2014 May 19.

Conversion from pillar[5]arene to pillar[6-15]arenes by ring expansion and encapsulation of C60 by pillar[n]arenes with nanosize cavities

Tomoki Ogoshi  1 , Naosuke Ueshima, Fumiyasu Sakakibara, Tada-aki Yamagishi, Takeharu Haino
Affiliations

Conversion from pillar[5]arene to pillar[6-15]arenes by ring expansion and encapsulation of C60 by pillar[n]arenes with nanosize cavities

Tomoki Ogoshi et al. Org Lett. .

Abstract

Conversion of ring size from pillar[5]arene to pillar[6-15]arenes and isolation of pillar[n]arene homologues (n = 11-13) with known pillar[n]arene homologues (n = 6-10) are demonstrated. Pillar[10]arene formed the most stable host-guest complex with C60 among the pillar[5-14]arenes.

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