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. 2014 Jun 16;53(12):5899-901.
doi: 10.1021/ic500964m. Epub 2014 Jun 3.

Cyanide-bridged decanuclear cobalt-iron cage

Takuya Shiga  1 , Tamaki Tetsuka, Kanae Sakai, Yoshihiro Sekine, Masayuki Nihei, Graham N Newton, Hiroki Oshio
Affiliations

Cyanide-bridged decanuclear cobalt-iron cage

Takuya Shiga et al. Inorg Chem. .

Abstract

A cyanide-bridged decanuclear [Co6Fe4] cluster was synthesized by a one-pot reaction, and the magnetic properties and electronic configuration were investigated. The complex displayed thermally controlled electron-transfer-coupled spin transition (ETCST) behavior between Co(III) low-spin-NC-Fe(II) low-spin and Co(II) high-spin-NC-Fe(III) low-spin states, as confirmed by single-crystal X-ray, magnetic, and Mössbauer analyses.

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