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. 2014 Oct 4;50(76):11093-6.
doi: 10.1039/c4cc02548b.

Platinum corroles

Abraham B Alemayehu  1 , Hugo Vazquez-Lima, Christine M Beavers, Kevin J Gagnon, Jesper Bendix, Abhik Ghosh
Affiliations

Platinum corroles

Abraham B Alemayehu et al. Chem Commun (Camb). .

Abstract

Platinum has been inserted into corroles for the first time and three oxidized Pt(IV)(corrole˙(2-))ArAr' complexes have been structurally characterized. The Soret maxima of these complexes exhibit an unusually strong dependence on the meso-aryl substituents on the corrole, indicating aryl → corrole˙(2-) charge transfer character in these transitions.

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