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. 2014 May 17;70(Pt 6):m209-10.
doi: 10.1107/S1600536814010095. eCollection 2014 Jun 1.

{Dimeth-yl [(phenyl-sulfon-yl)amido-]phosphato-κ(2) O,O'}bis-(tri-phenylphosphane-κP)copper(I)

Olesia V Moroz  1 , Viktor A Trush  1 , Tatiana Yu Sliva  1 , Kateryna O Znovjyak  1 , Vladimir M Amirkhanov  1
Affiliations

{Dimeth-yl [(phenyl-sulfon-yl)amido-]phosphato-κ(2) O,O'}bis-(tri-phenylphosphane-κP)copper(I)

Olesia V Moroz et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title complex, [Cu(C8H11NO5PS)(C18H15P)2], the Cu(I) ion is coordinated by two tri-phenyl-phosphane mol-ecules and two O atoms of the chelating dimeth-yl(phenyl-sulfon-yl)amido-phosphate anion, generating a squashed CuO2P2 tetrahedron. In the six-membered chelate ring, the Cu, P and O atoms are almost coplanar (r.m.s. deviation = 0.024 Å), with the N and S atoms displaced in the same direction, by 0.708 (5) and 0.429 (2) Å, respectively.

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Figures

Fig. 1.
Fig. 1.
Structural representation of I with atom numbering scheme and 50% probability thermal ellipsoid. The H atoms are omitted for clarity.
See this image and copyright information in PMC

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