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. 2014 May 17;70(Pt 6):o670.
doi: 10.1107/S160053681401085X. eCollection 2014 Jun 1.

N'-[(E)-3-Bromo-5-chloro-2-hy-droxy-benzyl-idene]furan-2-carbohydrazide

Affiliations

N'-[(E)-3-Bromo-5-chloro-2-hy-droxy-benzyl-idene]furan-2-carbohydrazide

A Sundar et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, C12H8BrClN2O3, the furan ring makes a dihedral angle of 17.2 (2)° with the six-membered ring. An intra-molecular O-H⋯N hydrogen bond stabilizes the mol-ecular conformation. In the crystal, N-H⋯O hydrogen bonds connect the mol-ecules into chains running along the c-axis direction. The crystal packing is additionally stabilized by C-H⋯O inter-actions into a three-dimensional supramolecular architecture.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of the title compound, showing the atomic numbering and displacement ellipsoids drawn at 30% probability level.
Fig. 2.
Fig. 2.
The crystal structure showing the R22(10) motif and also the formation of bifurcated R12(6) ring motif. For the sake of clarity, the H atoms not involved in the motif have been omitted.

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