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. 2014 Jul 2;136(26):9284-7.
doi: 10.1021/ja504990a. Epub 2014 Jun 18.

Iridium-catalyzed annulation of salicylimines with 1,3-dienes

Yusuke Ebe  1 , Takahiro Nishimura
Affiliations

Iridium-catalyzed annulation of salicylimines with 1,3-dienes

Yusuke Ebe et al. J Am Chem Soc. .

Abstract

Iridium-catalyzed annulation of salicylimines with 1,3-dienes gave high yields of the corresponding 4-aminochromanes with high stereoselectivity. The use of a chiral diene ligand enabled the asymmetric reaction to give 4-aminochromanes with high enantioselectivity.

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