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. 2014 Sep 25;50(74):10809-11.
doi: 10.1039/c4cc04816d.

Facile synthesis of ultra-small rhenium nanoparticles

Tuğçe Ayvalı  1 , Pierre Lecante, Pier-Francesco Fazzini, Angélique Gillet, Karine Philippot, Bruno Chaudret
Affiliations

Facile synthesis of ultra-small rhenium nanoparticles

Tuğçe Ayvalı et al. Chem Commun (Camb). .

Abstract

Ultra-small monodisperse rhenium nanoparticles (Re NPs; ca. 1.0-1.2 nm) were easily prepared by reducing the organometallic complex [Re2(C3H5)4] under a dihydrogen atmosphere under mild reaction conditions (3 bar H2; 120 °C). The particles can be stabilized by a ligand, hexadecylamine, or a polymer, polyvinylpyrrolidone and accommodate surface hydrides.

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