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. 2014 Sep 28;50(75):11043-5.
doi: 10.1039/c4cc04702h. Epub 2014 Aug 7.

Red-luminescent biphosphine stabilized 'Cu₁₂S₆' cluster molecules

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Red-luminescent biphosphine stabilized 'Cu₁₂S₆' cluster molecules

Xiao-Xun Yang et al. Chem Commun (Camb). .

Abstract

The synthesis, molecular structures and luminescence properties of two 'Cu12S6' cluster molecules with stabilizing bidentate phosphine ligands are described. Both display in the solid state at ambient temperature high photoluminescence quantum yields (≥48%) and good stability towards oxygen.

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