Red-luminescent biphosphine stabilized 'Cu₁₂S₆' cluster molecules
- PMID: 25098944
- DOI: 10.1039/c4cc04702h
Red-luminescent biphosphine stabilized 'Cu₁₂S₆' cluster molecules
Abstract
The synthesis, molecular structures and luminescence properties of two 'Cu12S6' cluster molecules with stabilizing bidentate phosphine ligands are described. Both display in the solid state at ambient temperature high photoluminescence quantum yields (≥48%) and good stability towards oxygen.
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