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. 2014 Jun 21;70(Pt 7):m272-3.
doi: 10.1107/S1600536814014081. eCollection 2014 Jul 1.

(η(6)-Benzene)(carbonato-κ(2) O,O')[di-cyclohex-yl(naphthalen-1-ylmeth-yl)phosphane-κP]ruthenium(II) chloro-form tris-olvate

Saravanan Gowrisankar  1 , Helfried Neumann  2 , Anke Spannenberg  2 , Matthias Beller  2
Affiliations

(η(6)-Benzene)(carbonato-κ(2) O,O')[di-cyclohex-yl(naphthalen-1-ylmeth-yl)phosphane-κP]ruthenium(II) chloro-form tris-olvate

Saravanan Gowrisankar et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title compound, [Ru(CO3)(η(6)-C6H6){(C6H11)2P(CH2C10H7)}]·3CHCl3, was synthesized by carbonation of [RuCl2(η(6)-C6H6){(C6H11)2P(CH2C10H7)}] with NaHCO3 in methanol at room temperature. The Ru(II) atom is surrounded by a benzene ligand, a chelating carbonate group and a phosphane ligand in a piano-stool configuration. The crystal packing is consolidated by C-H⋯O and C-H⋯Cl hydrogen-bonding inter-actions between adjacent metal complexes and between the complexes and the solvent mol-ecules. The asymmetric unit contains one metal complex and three chloro-form solvent mol-ecules of which only one was modelled. The estimated diffraction contributions of the other two strongly disordered chloro-form solvent mol-ecules were substracted from the observed diffraction data using the SQUEEZE procedure in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148-155].

Keywords: crystal structure.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of the title compound with atoms at the 30% probability level for the displacement ellipsoids. Hydrogen atoms are omitted for clarity.
Fig. 2.
Fig. 2.
A packing diagram of the title compound showing hydrogen bonds as dashed lines.
See this image and copyright information in PMC

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