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. 2014 Jul 2;70(Pt 8):m288.
doi: 10.1107/S1600536814013130. eCollection 2014 Aug 1.

Poly[μ6-(naphthalene-2,6-di-carboxyl-ato)-bis-(aqua-lithium)]

Lionel Fédèle  1 , Frédéric Sauvage  1 , Matthieu Becuwe  1 , Jean-Noël Chotard  1
Affiliations

Poly[μ6-(naphthalene-2,6-di-carboxyl-ato)-bis-(aqua-lithium)]

Lionel Fédèle et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title compound, [Li2(C12H6O4)(H2O)2] n , crystallizes with one half of the molecular entities in the asymmetric unit. The second half is gererated by inversion symmetry. The crystal structure has a layered arrangement built from distorted edge-sharing LiO3(OH)2 tetra-hedra parallel to (100), with naphthalenedi-carboxyl-ate bridging the LiO3(OH)2 layers along the [100] direction. Hydrogen bonding between the water molecule and adjacent carboxylate groups consolidates the packing.

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Figures

Fig. 1.
Fig. 1.
Molecular view of the title compound. Li, O, C, and H atoms are represented by light green, red, brown and white spheres respectively
Fig. 2.
Fig. 2.
Crystal structure of the title compound view along the b axis. Layers of LiO3(OH2) edge-sharing tetrahedra in the (yz) plane are connected via naphthalene dicarboxylate molecules.
See this image and copyright information in PMC

References

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