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. 2014 Jul 5;70(Pt 8):o850.
doi: 10.1107/S1600536814015256. eCollection 2014 Aug 1.

2-[(4,6-Di-amino-pyrimidin-2-yl)sulfan-yl]-N-(2-methyl-phen-yl)acetamide

S Subasri  1 , Timiri Ajay Kumar  2 , Barji Nayan Sinha  2 , Venkatesh Jayaprakash  2 , Devadasan Velmurugan  1
Affiliations

2-[(4,6-Di-amino-pyrimidin-2-yl)sulfan-yl]-N-(2-methyl-phen-yl)acetamide

S Subasri et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, C13H15NOS, the plane of the pyrimidine ring makes a dihedral angle of 54.73 (9)° with that of the o-tolyl ring. The mol-ecule adopts an extended conformation, which is evident from the C-C(=O)-N-Car (ar = aromatic) torsion angle of 178.42 (15)°. In the crystal, mol-ecules are linked via pairs of N-H⋯N hydrogen bonds, forming inversion dimers with an R (2) 2(8) ring motif. The dimers are linked by N-H⋯O and C-H⋯O hydrogen bonds, with the O atom accepting three such interactions, forming sheets parallel to (100).

Keywords: crystal structure.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of the title molecule, with atom labelling. Displacement ellipsoids are drawn at the 30% probability level.
Fig. 2.
Fig. 2.
The crystal packing of the title compound, viewed along the b axis. The hydrogen bonds are shown as dashed lines (see Table 1 for details; the C and N-bound H-atoms not involved in hydrogen bonding have been omitted for clarity).
See this image and copyright information in PMC

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