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. 2014 Nov 24;53(48):13269-72.
doi: 10.1002/anie.201406311. Epub 2014 Sep 26.

Synthesis of chlorosilicates

Simon Steinhauer  1 , Tobias Böttcher, Nico Schwarze, Beate Neumann, Hans-Georg Stammler, Berthold Hoge
Affiliations

Synthesis of chlorosilicates

Simon Steinhauer et al. Angew Chem Int Ed Engl. .

Abstract

Chlorosilicates represent important intermediates in S(N)2 reactions of chlorosilanes. They can be stabilized by the introduction of electron-withdrawing substituents. Salts of various (pentafluoroethyl)chlorosilicates have been isolated and structurally characterized.

Keywords: Lewis acids; electron-withdrawing groups; nucleophilic substitution; silicates; solvent effects.

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