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. 2014 Dec 19;16(24):6464-7.
doi: 10.1021/ol5032987. Epub 2014 Dec 8.

Calcium(II)-catalyzed aza-Piancatelli reaction

David Lebœuf  1 , Emmanuelle Schulz, Vincent Gandon
Affiliations

Calcium(II)-catalyzed aza-Piancatelli reaction

David Lebœuf et al. Org Lett. .

Abstract

The first examples of calcium-catalyzed aza-Piancatelli reactions between substituted 2-furylcarbinols and aniline derivatives are described. A variety of 4-aminocyclopentenones have been synthesized stereoselectively in high yields. The experimental procedure utilizes simple salts and does not require specific precautions.

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