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. 2015 Jan 16;17(2):176-9.
doi: 10.1021/ol503455r. Epub 2014 Dec 31.

Catalytic asymmetric construction of pyrroloindolines via an in situ generated magnesium catalyst

Linqing Wang  1 , Dongxu Yang, Fengxia Han, Dan Li, Depeng Zhao, Rui Wang
Affiliations

Catalytic asymmetric construction of pyrroloindolines via an in situ generated magnesium catalyst

Linqing Wang et al. Org Lett. .

Abstract

An asymmetric formal [3 + 2]-cycloaddition between meso-aziridines and C3-alkylindoles mediated by an in situ generated magnesium catalyst was developed for asymmetric construction of pyrroloindolines. A variety of pyrroloindolines could be obtained by employing commercial available ligands with the assistance of an easily prepared achiral ligand.

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