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. 2015 Mar 12;119(10):4048-52.
doi: 10.1021/jp512128c. Epub 2015 Feb 26.

Hyperpolarized para-ethanol

Daniele Mammoli  1 , Basile Vuichoud, Aurélien Bornet, Jonas Milani, Jean-Nicolas Dumez, Sami Jannin, Geoffrey Bodenhausen
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Free article

Hyperpolarized para-ethanol

Daniele Mammoli et al. J Phys Chem B. .
Free article

Abstract

We show that an imbalance between the populations of singlet (S) and triplet (T) states in pairs of magnetically equivalent spins can be generated by dissolution dynamic nuclear polarization. In partly deuterated ethanol (CD3(13)CH2OD), this T/S imbalance can be transferred by cross-relaxation to observable, enhanced signals of protons and coupled (13)C.

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