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. 2015 Apr 1;27(13):2177-81.
doi: 10.1002/adma.201405244. Epub 2015 Feb 11.

Mn2FeWO6 : A new Ni3TeO6-type polar and magnetic oxide

Affiliations

Mn2FeWO6 : A new Ni3TeO6-type polar and magnetic oxide

Man-Rong Li et al. Adv Mater. .

Erratum in

  • Mn2FeWO6: A New Ni3TeO6 -Type Polar and Magnetic Oxide.
    Li MR, Croft M, Stephens PW, Ye M, Vanderbilt D, Retuerto M, Deng Z, Grams CP, Hemberger J, Hadermann J, Li WM, Jin CQ, Saouma FO, Jang JI, Akamatsu H, Gopalan V, Walker D, Greenblatt M. Li MR, et al. Adv Mater. 2016 Mar 16;28(11):2098. doi: 10.1002/adma.201600479. Adv Mater. 2016. PMID: 26970066 No abstract available.

Abstract

Mn(2+)2 Fe(2+)W(6+)O6 , a new polar magnetic phase, adopts the corundum-derived Ni3TeO6 -type structure with large spontaneous polarization (PS) of 67.8 μC cm(-2), complex antiferromagnetic order below ≈75 K, and field-induced first-order transition to a ferrimagnetic phase below ≈30 K. First-principles calculations predict a ferrimagnetic (udu) ground state, optimal switching path along the c-axis, and transition to a lower energy udu-udd magnetic double cell.

Keywords: Mn2FeWO6; first-principles calculations; magnetic phase diagrams; multiferroics; polar magnets.

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