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. 2015 Mar 18;51(22):4579-82.
doi: 10.1039/c5cc00784d.

Dinuclear zinc catalysts with unprecedented activities for the copolymerization of cyclohexene oxide and CO2

S Kissling  1 , M W Lehenmeier, P T Altenbuchner, A Kronast, M Reiter, P Deglmann, U B Seemann, B Rieger
Affiliations

Dinuclear zinc catalysts with unprecedented activities for the copolymerization of cyclohexene oxide and CO2

S Kissling et al. Chem Commun (Camb). .

Abstract

A variety of new dinuclear zinc catalysts was developed and tested for the copolymerization of cyclohexene oxide and carbon dioxide. Electron-withdrawing groups thereby led to unprecedented activities with turnover frequencies up to 155,000 h(-1). These are by far the highest polymerization rates ever reported for the copolymerization of cyclohexene oxide and CO2.

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