Review
doi: 10.1002/asia.201403248.
Epub 2015 Feb 12.
Iodine-catalyzed oxidative coupling reactions utilizing C - H and X - H as nucleophiles
Affiliations
- PMID: 25683644
- DOI: 10.1002/asia.201403248
Item in Clipboard
Review
Iodine-catalyzed oxidative coupling reactions utilizing C - H and X - H as nucleophiles
Chem Asian J.
2015 Apr.
Abstract
In recent decades, iodine-catalyzed oxidative coupling reactions utilizing C - H and X - H as nucleophiles have received considerable attention because they represent more efficient, greener, more atom-economical, and milder bond-formation strategies over transition-metal-catalyzed oxidative coupling reactions. This Focus Review gives a brief summary of recent development on iodine-catalyzed oxidative coupling reactions utilizing C - H and X - H as nucleophiles.
Keywords: cross-coupling; iodine; nucleophiles; oxidation; reaction mechanisms.
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Similar articles
-
Molecular iodine catalyzed cross-dehydrogenative coupling reaction between two sp3 C-H bonds using hydrogen peroxide.Org Lett. 2013 Feb 1;15(3):574-7. doi: 10.1021/ol303389t. Epub 2013 Jan 18. Org Lett. 2013. PMID: 23331076
-
Photocatalytic Activation of Less Reactive Bonds and Their Functionalization via Hydrogen-Evolution Cross-Couplings.Acc Chem Res. 2018 Oct 16;51(10):2512-2523. doi: 10.1021/acs.accounts.8b00267. Epub 2018 Oct 3. Acc Chem Res. 2018. PMID: 30280898
-
Iodine Catalyzed Oxidative Synthesis of Quinazolin-4(3H)-ones and Pyrazolo[4,3-d]pyrimidin-7(6H)-ones via Amination of sp(3) C-H Bond.J Org Chem. 2015 Jul 2;80(13):6915-21. doi: 10.1021/acs.joc.5b00989. Epub 2015 Jun 23. J Org Chem. 2015. PMID: 26067767
-
Palladium-catalyzed cross-dehydrogenative functionalization of C(sp(2))-H Bonds.Chem Asian J. 2014 Jan;9(1):26-47. doi: 10.1002/asia.201300990. Epub 2013 Oct 2. Chem Asian J. 2014. PMID: 24123795 Review.
-
Oxidative trifluoromethylation and trifluoromethylthiolation reactions using (trifluoromethyl)trimethylsilane as a nucleophilic CF3 source.Acc Chem Res. 2014 May 20;47(5):1513-22. doi: 10.1021/ar4003202. Epub 2014 Apr 28. Acc Chem Res. 2014. PMID: 24773518 Review.
Cited by
-
(Diacetoxy)iodobenzene-Mediated Regioselective Imidation of Imidazoheterocycles with N-Fluorobenzenesulfonimide.ACS Omega. 2018 Oct 3;3(10):12505-12512. doi: 10.1021/acsomega.8b02088. eCollection 2018 Oct 31. ACS Omega. 2018. PMID: 31457983 Free PMC article.
-
Molecular iodine-catalyzed one-pot multicomponent synthesis of 5-amino-4-(arylselanyl)-1H-pyrazoles.Beilstein J Org Chem. 2018 Nov 6;14:2789-2798. doi: 10.3762/bjoc.14.256. eCollection 2018. Beilstein J Org Chem. 2018. PMID: 30498528 Free PMC article.
-
Cross-dehydrogenative coupling and oxidative-amination reactions of ethers and alcohols with aromatics and heteroaromatics.Chem Sci. 2017 Sep 1;8(9):5845-5888. doi: 10.1039/c7sc01045a. Epub 2017 Jun 30. Chem Sci. 2017. PMID: 28970941 Free PMC article.
-
Cross-Dehydrogenative N-N Coupling of Aromatic and Aliphatic Methoxyamides with Benzotriazoles.Org Lett. 2021 May 21;23(10):3902-3907. doi: 10.1021/acs.orglett.1c01034. Epub 2021 May 11. Org Lett. 2021. PMID: 33974802 Free PMC article.
-
I2/DMSO-mediated oxidative C-C and C-heteroatom bond formation: a sustainable approach to chemical synthesis.RSC Adv. 2024 Feb 14;14(9):5817-5845. doi: 10.1039/d3ra08685b. eCollection 2024 Feb 14. RSC Adv. 2024. PMID: 38362068 Free PMC article. Review.
Publication types
MeSH terms
Substances
LinkOut - more resources
Full Text Sources
Other Literature Sources
